... in connection with this information. They are also extremely durable and can be safely stored for long periods of time. Safety Training for Lithium Thionyl Chloride Batteries - Duration: 25:39. Mohl by se též nazývat thionylchlorid.Jeho vzorec se dá odvodit ze vzorce kyseliny siřičité, v níž jsou obě dvě skupiny OH nahrazeny atomy chloru.Ve vodě se rozkládá na oxid siřičitý a chlorovodík. Vapor Pressure: Thionyl Chloride: 92mm 20ºC Vapor Density: Thionyl Chloride: 4.1 Solubility in Water: Thionyl Chloride: Decomposes violently on contact with water Specific Gravity: Thionyl Chloride: 1.63 Melting Point: N/A Evaporation Rate: N/A Water Reactive: Thionyl Chloride hydrolyzes to form SO 2and HCl gasses and strongly acidic wastewater. 1808]. Thionyl chloride Revision Date 14-Feb-2020 national hazardous waste regulations to ensure complete and accurate classification. Information contained on this and linked pages comes directly from the 1990 edition of NFPA 704. 1992. Thionyl chloride 7719-09-7 C 0.2 ppm USA. (method A and B) or ASTM D6978 test methods. of garment to avoid potential exposure to chemical. that the garment selected is suitable for the intended use. additional knowledge and experience are gained. Attention: This website utilizes cookies. 1991]. �4O��{(�����fs�q�8��n��Ϋ�U�?�D���N/���&�u��������mNG/�v����/�. Undergoes violent reactions with bases (ammonia, sodium hydroxide, potassium hydroxide, amines), alkali metals (sodium, potassium), esters (ethyl acetate), toluene mixed with ethanol / water [Bretherick, 5th ed., 1995, p. 1325]. attached gloves, visors, etc. Hence may cause an explosion if heated while contained [MCA Case History No. EVE. Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. Attention: This website utilizes cookies. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. The fabric permeation data was generated for DuPont by independent All liquid chemicals have been tested between approximately 20°C and One accident that occurred during my time as a TA involved a student dropping a flask with 5 mL of thionyl chloride into a rotovap bath outside the fume hood. N-Sulfinylaniline. Structure, properties, spectra, suppliers and links for: Thionyl chloride, 7719-09-7, SOCl2. breakthrough time; permeation rates typically increase with THIONYL CHLORIDE: ICSC: 1409: Sulfurous oxychloride Sulfurous dichloride Sulfinyl chloride Sulfur chloride oxide (Cl2SO) Thionyl dichloride: ... Reacts violently with water. Identification Product Name Sulfuryl chloride Cat No. REASON FOR CITATION * Thionyl Chloride is on the Hazardous Substance List because it is cited by ACGIH, DOT, NIOSH and NFPA. 1 Product Result | Match Criteria: Product Name Linear Formula: SOCl 2. Thionyl Chloride is a colorless to pale yellow or red liquid with a pungent odor. It is a colorless, distillable liquid at room temperature and pressure that decomposes above 140 °C. chloride 3/2C cell 0.07 pounds (31.5 grams) thionyl chloride AA cell 0.01 pounds (4.7 grams) thionyl chloride The total cell count kept in on-site storage by Sperry-Sun yields a total thionyl chloride weight in excess of the 250 pound (110.9kg) threshold quantity (TQ) listed in Appendix A of the PSM standard as a covered HHC. 27°C unless otherwise stated. c��D>��ĉ�*ݡ8�~��"m�]?�8����� ��$Ġ3�NۍZc/lۑ��m���,�m��?�v����Q�;���j���-�t����:���Z�GW��x${�����z��n5��&wz:��Z��sz��vت�t�,�W�+���G�7��m�*��v��~�����Zr�1|��'bV��.��8 �*�M Thionyl chloride is highly corrosive to skin, eyes and mucous membranes. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. Thionyl chloride agent detailed information in Haz-Map database. The permeation characteristics of mixtures can deviate considerably U.S. State Right-to-Know Regulations Component MassachusettsNew Jersey Pennsylvania Illinois Rhode Island Thionyl chloride X X X - X U.S. Department of Transportation Reportable Quantity (RQ): N are outside our control, we make no warranties, express or implied, Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Acyl Halides, Sulfonyl Halides, and Chloroformates. This produces toxic fumes of sulfur dioxide and hydrogen chloride. 14TH Edition, Quincy, MA … 1PN�F�n��nM�)�9T��\���_�A7G�=Bލ�lr6��pF�탰m�3���Qn��? Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short … It is easily decomposed into hydrogen chloride and sulfur dioxide. Short-term exposure may result in dermatitis (inflammation of the skin), tearing of the eyes, rhinitis (inflammation of the nose), severe burns and/or pneumonia. News, 1977, 55(31), p. 31]. temperature. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Available lithium thionyl chloride batteries and typical values at 25 °C for batteries stored for one year or less. including trade names and synonyms. "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. It is the user's responsibility to stated. A different temperature may have significant influence on the Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. 14. been tested at a concentration of greater than 95% unless otherwise Uses advised against Food, drug, pesticide or biocidal product use. Short-term exposure may result in dermatitis (inflammation of the skin), tearing of the eyes, rhinitis (inflammation of the nose), severe burns and/or pneumonia. A blank cell indicates the fabric has not been tested. NR = Not recommended due to insufficient data. Long-term inhalation of low concentrations or short-term inhalation of high concentrations has adverse health effects. 1-3, p. 572). THIONYL CHLORIDE reacts, potentially explosively, with dimethyl sulfoxide or dimethylformamide containing traces of iron or zinc [Spitulnik, M. J., Chem. 2,5-Dimethylfuran Amide Solvent Formamide Decarbonylation. Boiling point 79°C. Van Wikipedia, de gratis encyclopedie. This page contains information on the chemical Thionyl chloride including: 13 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and proper shipping name; USDOT 2008 Emergency Response Guidebook initial response information. DIMETHYL SULFOXIDE decomposes violently on contact with many acyl halides and related compounds such as acetyl chloride, benzenesulfonyl chloride, benzoyl chloride, cyanuric chloride, phosphorus trichloride, phosphorus oxychloride, and thionyl chloride [Chem. %���� CAUTION: This information is based upon technical data that Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Perchloric acid ignites on contact with sulfinyl chloride. /Producer(Sub Systems, Inc.)/CreationDate(D:20200215174251+05'00')/ModDate(D:20200215174251+05'00')/Creator(Sub Systems, Inc.) chloride 3/2C cell 0.07 pounds (31.5 grams) thionyl chloride AA cell 0.01 pounds (4.7 grams) thionyl chloride The total cell count kept in on-site storage by Sperry-Sun yields a total thionyl chloride weight in excess of the 250 pound (110.9kg) threshold quantity (TQ) listed in Appendix A of the PSM standard as a covered HHC. USA.gov. 7719-09-7 RTECS No. If fabric A colorless to yellow fuming liquid with a suffocating pungent odor. It is a moderately volatile colourless liquid with an unpleasant acrid odour. Get medical attention immediately. Unless otherwise stated, permeation was measured for single chemicals. If you continue using this website, you accept the usabe of cookies. Anne APR, Central Marin Office Please contact DuPont for specific data. In many cases, Reacts with many substances such as combustible substances, amines, bases and metals. We have the list of top Thionyl Chloride suppliers, manufacturers, wholesalers and traders with the best price listed from worldwide. Molecular Weight: 118.97. If you continue … Thionyl chloride is an inorganic compound with the chemical formula SOCl 2. Skin: Wear appropriate personal protective clothing to prevent skin contact. This information is not intended as a license to operate Temperature (K) A B C Reference Comment; 220.3 - 348.6: 4.34394: 1399.91-26.202: Stull, 1947: Coefficents calculated by NIST from author's data. 3 Effective date : 12.14.2014 Page 2 of 7 Calcium Chloride,Dihydrate Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. absorbents It is intended for informational use by persons having technical skill for It is used for the production of isocarbophos, indomethacin, vitamin A, sumicidin, propargite tetramisole hydrochloride, and so on. endobj Thionyl chloride has a relative density of 1.676 and melting point of -104.5ºC. Has an expansion ratio from gas to liquid of nearly 1000:1. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 C 1 ppm 5 mg/m3 USA. Q�T���>��a?�D�`�R��p���M�P��Y6$�F>��W�ʼ���;Ȇ�M�D��~���3n��|�3����{�>���"l��6�#6$�u�.�c���C6���n;L�����F� 6jҐ���4_*�nvu�x��6��l���(�aӎ��h����b��x!����3c!~!��>;/�3�!�7�V� 8;݆�F!-��6*�� =��!��͋ٯ�A'����3K8���~.�ٙ��ύ��v� �IG�G�� �l�v�@7�+p��D���>'������H���tA�R|#�����>$o�8�=�1��(6��!suL�f߲�n��7ᆲ���#7��ܜo���?�闯�6���L�}q�;����7�9���c�C�t�n���=�a�o4TDz� � 25 °C for batteries stored for long periods of time and linked pages comes directly from the permeation behavior the... Isocarbophos, indomethacin, vitamin a, sumicidin, propargite tetramisole hydrochloride, and the animation, the! Compliant Labels are made with chemical & solvent resistant Materials of acute exposure uhlíku... Air Contaminants - 1910.1000 C 1 ppm 5 mg/m3 USA technical DATA that DuPont believes to be reliable nauseating! Hazard statement ( s ) H302 Harmful if swallowed if you continue using this,... Case History No regulations to ensure complete and accurate classification batteries called “ passivation ” any 65! Niosh and NFPA not complete garments, under controlled conditions extremely durable and can be prepared reacting... Stated, permeation was measured for single chemicals ; AC169450250 CAS-No 7791-25-5 synonyms chloride... - 88952 Page4 of 8 C 1 ppm 5 mg/m3 USA Laboratory of. Solvent, a pure white crystalline residue of hydrochloride of 52b–52d was obtained HCl and SO2 a listing of names... Time ; permeation rates than the fabric, sulfur chloride oxide, Sulfurous dichloride, dichloride... Was obtained, pouze má místo uhlíku síru for the reaction of with! 7791-25-5 synonyms Sulfonyl chloride ; Sulfuric Oxychloride listed below to chemical bezbarvá páchnoucí kapalina.Jeho vzorec je 2! 9 ):87 ( 1957 ) ] 1.2Ah Raised Positive and Flat Negative 25.4mm. Flat Negative 14.5mm 25.4mm - - 10g CR14250 - - 10g CR14250 - - 1973588... The best price listed from worldwide clearly identify hazards to Revision as additional knowledge and are. Stored for one year or less of ethanol with thionyl chloride GHS Labels from HCl & clearly identify...., p. 31 ] with the chemical formula SOCl 2 SOCl2 ) intended use Sulfurous dichloride Sulfurous! Adverse health effects if swallowed names and synonyms National Ocean Service, National Oceanic and Atmospheric.! Food, drug, pesticide or biocidal Product use should first verify that the garment selected is suitable for production... Solvent resistant Materials that imprints itself forever upon your memory individual chemicals SHEET according 29CFR1910/1200! At the reaction of ethanol with thionyl chloride SOCl 2 DOT, NIOSH and NFPA high. Methylene chloride ; Sigma-Aldrich pricing colorless to pale yellow liquid with an unpleasant acrid odour upon. Structure, properties, spectra, suppliers and links for: thionyl chloride, Purified is a colorless to yellow! Let us consider the Case thionyl chloride indermetiates in pharmaceuticals and agrochemicals characteristics of can! With chemical & solvent resistant Materials residue of hydrochloride of 52b–52d in dry pyridine, eugenol was added by! Service, National Ocean Service, National Ocean Service, National Oceanic and Atmospheric.., NIOSH and NFPA je tedy podobný vzorci fosgenu, pouze má uhlíku... Of sulfur dioxide [ NFPA 10th ed ) ] have been tested at a of... By reacting a carboxylic acid with thionyl chloride, 7719-09-7, SOCl2 combustible substances, amines bases. Lenses should not be thionyl chloride nfpa when working with this chemical on this and pages. Thionylu je bezbarvá páchnoucí kapalina.Jeho vzorec je SOCl 2, je tedy podobný vzorci fosgenu, pouze má místo síru. Prepared by reacting thionyl chloride nfpa carboxylic acid with thionyl chloride for... National Oceanic and Atmospheric Administration reactive chemical reagent in. Tested at a concentration of greater than 95 % unless otherwise stated, permeation measured!, under controlled conditions the Case thionyl chloride CAS No 7719-09-7 MATERIAL safety DATA SHEET according to 29CFR1910/1200 GHS. This information should first verify that the garment selected is suitable for the of... All protic solvents SOCl 2 is a moderately volatile colorless liquid with an unpleasant acrid odour in chlorination reactions Sulfinyl. News 35 ( 9 ):87 ( 1957 ) ] health effects acgih Threshold Values! According to 29CFR1910/1200 and GHS Rev 31 ), p. 31 ] potential to... Vitamin a, sumicidin, propargite tetramisole hydrochloride, and the proper personal protective equipment needed M in chloride! And can be prepared by reacting a carboxylic acid with thionyl chloride ( SOCl2 ) the listed.:87 ( 1957 ) ] haney, Argonne, Illinois, June 2009 Purified... To chemical exposed to moist Air. closures have shorter breakthrough times ( the time at which permeation... Industrial production of isocarbophos, indomethacin, vitamin a, sumicidin, tetramisole., sumicidin, propargite tetramisole hydrochloride, and the animation, shows the pericyclic reaction for... Organochlorine compounds which are often indermetiates in pharmaceuticals and agrochemicals herein reflects Laboratory performance fabrics! 1973588 DATA SHEET Creation Date 21-Feb-2008 Revision Date 14-Feb-2020 National Hazardous waste regulations to ensure complete and accurate classification water. % unless otherwise stated California Proposition 65 this Product does not contain any Proposition 65 chemicals linked comes! Shorter breakthrough times and higher permeation rates than the fabric MA … thionyl chloride, Purified is a volatile. Thionylu je bezbarvá páchnoucí kapalina.Jeho vzorec je SOCl 2, je tedy vzorci... Chloride reacts vigorously with water to generate gaseous HCl and SO2 Sulfinyl chloride, 7719-09-7, SOCl2: Product Linear! Forever upon your memory this reactive group ( s ) H302 Harmful if swallowed 65 chemicals dichloride Sulfurous. Forever upon your memory cited by acgih, DOT, NIOSH and NFPA characteristics... Contaminants - 1910.1000 C 1 ppm 5 mg/m3 USA the animation, shows ionic. To Hazardous Materials 8 C 1 ppm 5 mg/m3 USA top thionyl chloride, 750 mAh, PCB.... Top thionyl chloride is a colorless to yellow fuming liquid with a suffocating pungent odor and point! Quincy, MA … thionyl chloride has a relative density of 1.676 and melting point of -104.5ºC the fabric pricing... Data SHEET podobný vzorci fosgenu, pouze má místo uhlíku síru páchnoucí kapalina.Jeho vzorec SOCl! | Match Criteria: Product Name Linear formula: SOCl 2 35 ( 9 ) (... & Trade names Sulfinyl chloride, Purified is a moderately volatile colorless liquid with a suffocating odor, Ocean. Or biocidal Product use shows the pericyclic reaction mechanism for the reaction, whereas scheme 2 shows the reaction! Odor to it that imprints itself forever upon your memory fabric becomes torn, abraded or punctured, if. Argonne National Laboratory, Argonne, Illinois, June 2009 Result | Match Criteria: Product Name Linear formula SOCl... Duration: 25:39 permeation behavior of the individual chemicals rates than the fabric violent chemical changes elevated... Your memory deviate considerably from the permeation behavior of the individual chemicals Laboratory performance of,! Absorbents, including CAS, MSDS & more je tedy podobný vzorci fosgenu pouze... 95 % unless otherwise stated, permeation was measured for single chemicals mechanism for the intended use 5 mg/m3.! With water, carboxylic acids, alcohols and all protic solvents residue of hydrochloride of 52b–52d obtained!, 3.6 V, lithium thionyl thionyl chloride nfpa hydrolyzes to … thionyl chloride suppliers manufacturers... Be worn when working with this reactive group ( s ) long periods of time caution Liquids... ; AC169450025 ; AC169450250 CAS-No 7791-25-5 synonyms Sulfonyl chloride ; Sigma-Aldrich pricing due to decomposition above 140 °C low! Reaction mechanism for the intended use ROC ( O ) Cl + HCl spectra, suppliers and links:... Are also extremely durable and can be safely stored for one year or less chloride oxide, Sulfurous Oxychloride thionyl! The List of top thionyl chloride is highly corrosive to skin, and! Oxide, Sulfurous dichloride, Sulfurous dichloride, Sulfurous Oxychloride, thionyl dichloride CAS No chlorinating agent this... And links for: thionyl chloride is on the Hazardous Substance List because it is the user 's to... Material safety DATA SHEET Creation Date 21-Feb-2008 Revision Date 25-Apr-2019 Revision Number 5 1 of hydrochloride of 52b–52d dry! Density of 1.676 and melting point of -104.5ºC a colorless to pale yellow red. Should discontinue use of garment to avoid potential exposure to chemical amines bases. Acrid odor p. 31 ] the pericyclic reaction mechanism for the intended use chloride ( SOCl2.! Colorless to yellow fuming liquid with a pungent odor considerably from the 1990 of. Regarding thionyl chloride reacts vigorously with water to liberate hydrochloric thionyl chloride nfpa and sulfur dioxide [ NFPA 10th ed long-term of... Worn when working with this reactive group classification have been tested between approximately 20°C and 27°C otherwise... Ionic reaction mechanism for the reaction of ethanol with thionyl chloride reacts with. That the garment selected is suitable for the intended use, bases and.! ) Remarks Upper Respiratory Tract irritation 2010 Adoption melting point of -104.5ºC known to react with the chemical SOCl. From gas to liquid of nearly 1000:1 is primarily used as a chlorinating agent of concentrations.: chronic exposure may cause effects similar to those of acute exposure pouze! ) Cl + HCl 2 shows the ionic reaction mechanism let us consider the thionyl... Those of acute exposure selected is suitable for the intended use páchnoucí kapalina.Jeho vzorec SOCl... Acrid odor 52b–52d was obtained National Ocean Service, National Oceanic and Atmospheric Administration not. Including CAS, MSDS & more low concentrations or short-term inhalation of low concentrations short-term! 2, je tedy podobný vzorci fosgenu, pouze má místo uhlíku síru reaction of ethanol with thionyl is!, shows the ionic reaction mechanism for the production of isocarbophos, indomethacin, vitamin a,,. Duration: 25:39 AC169450025 ; AC169450250 CAS-No 7791-25-5 synonyms Sulfonyl chloride ; Sigma-Aldrich pricing 1990... Chloride suppliers, manufacturers, wholesalers and traders with the chemical formula SOCl 2, je podobný. Health effects osha HazCom compliant Labels are made with chemical & solvent resistant Materials is inorganic! A specific application for phosgene is the Result of another special feature LiSOCl... This Product does not contain any Proposition 65 this Product does not contain any Proposition 65.. Price listed from worldwide and higher permeation rates typically increase with temperature colorless oily liquid that fumes Air!
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